Spectro Scientific Blog

Elemental Analysis of Oil

Posted by John Morgan on October 13, 2017

Introduction

SpectrOil_100 Series_3QtrLeft_5061_WithArc_NB2017sm.pngThe basis of modern oil analysis programs is the use of optical emission spectroscopy (OES) to measure the ppm (parts per million) levels of wear metals, contaminants, and additives in oil samples. Whatever an oil lab may need to measure, multi-elemental analysis is the core of an in-service oil analysis program. This paper gives an overview of Rotating Disc Electrode Optical Emission Spectroscopy (RDE-OES), its applications, and the SpectrOil Series family of products, which combine the latest innovations for increased performance and reliability with 30+ years of experience in military and laboratory applications.

Early Background

Sometime after World War II, the Denver and Rio Grande Railroad, now defunct, began analyzing diesel locomotive engine oil by looking at the spectral lines emitted by an in service oil sample when excited by a strong electric arc using carbon electrodes. Early tests proved that monitoring the elements attributed to wear and contamination provided early warnings of chronic equipment failure.

Elemental spectroscopy is the backbone of an oil analysis program as it is widely applicable to a closed loop
lubricating system such as those found in gas turbines, diesel and gasoline engines, transmissions, gearboxes,
compressors and hydraulic systems. In practice, an oil sample is periodically taken from a system and analyzed. The resulting data, when compared to previous analyses and allowable limits, may indicate a sound mechanical system showing only normal wear, or it may point out a potentially serious problem in its early stages. With this advanced warning, steps may be taken to correct the situation before serious damage or injury occurs.

Spectroscopic oil analysis works by detecting the fine particles generated by relative motion of metallic parts in an oil-wetted system. Contaminants are also detected and lubricant mix-ups, or badly degraded lubricants, are identified by the concentration of additive elements. Multielement analysis, coupled with knowledge of the materials used to build the engine, often allows identification of a specific component in distress.

Table 1 shows that typical metal elements can be analyzed by spectroscopy and their typical sources.

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Principles of Spectroscopy

Spectroscopy is a technique for detecting and quantifying the presence of elements in a material. Spectroscopy
utilizes the fact that each element has a unique atomic structure, and when subjected to the addition of energy, each element emits light of specific wavelengths or colors. If this light is dispersed by using a dispersing element, such as a prism, a line spectrum will result. Since no two elements have the same pattern of spectral lines, the collected light can be analyzed and each element contained in the sample identified. Additionally, the intensity of the emitted light is proportional to the quantity of the element present in the sample, allowing the concentration of that element to be determined.

These spectral lines are unique to the atomic structure of only one element. For the hydrogen atom, with an atomic
number of 1, the spectrum is fairly simple (Figure 1). On the other hand, the spectrum of iron with an atomic number of 26 is much more complicated with many emission lines in the visible spectrum corresponding to the many possible electronic transitions that may occur (Figure 2). If more than one element is present in the sample, spectral lines of distinctively different wavelengths will appear for each element. These lines must be separated in order to identify and quantify the elements present in the sample. Usually only one spectral line among many is chosen to determine the concentration of a certain element. This line is chosen for its intensity and freedom from spectral line interference of other elements. To accomplish this, an optical system is required.

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